SHA-2 is a set of hashing algorithms, such as SHA-256, designed by the NSA, and is a component of NSA Suite B. Laserfiche 9.1 has made several changes mentioned in KB 1013370 (the KB Ramon linked above), to support the various algorithms specified by Suite B.
However, which certificates types are supported for SSL should not be dependent on Laserfiche at all: Laserfiche can use SSL, but we do not have our own implementation of SSL. Whether or not you can use SHA-2 certificates for SSL should only be dependent on whether your machines support it. Microsoft has an article on SHA-2 support in Windows. Windows 2008, Vista, and 7 all support SHA-2 out of the box. 2003 and XP can download service packs or hotfixes, but XP still does not have full support with the service pack.
For more information on configuring SSL on the Laserfiche Server on Windows 2008+, Vista, or 7, see Matthew's answer to this previous post.
In short, if you are using Windows 2008 or Vista or newer, you should not have issues using SHA-2 certificates for SSL (you may also be able to use SHA-2 certificates on XP or Windows 2003 machines, but it will require more setup).