HI Sam
So actually the Link group was not appropriate for our use here as one document is a parent (an application) and all other files associated with that are children documents (supporting documents, plans, drawings, certification of staff, etc....)
Luckily, the document relationship is available in workflow as an activity so that worked out very well.
I do not really agree that the admin guide describes the difference very well between the two options:
Document links allow users to connect more than one document to one another. There are two types of links: document relationships, which connect two documents, and link groups, which connect larger groups of documents.
You can use document relationships to connect two related documents, such as e-mails and attachments or meeting agendas and agenda packets. Link groups are used to collect any number of related documents, such as all yearly reports, or all documents relation to a particular case.
That did not answer my original question and that is why I started this question.
In my use case it makes a lot more sense to have distinct relationships to the parent, and while I would like to have the children file linked together intermixed as well that is not as important as attributing the children to the parent file with a distinct relationship, which I do not think the Link Group can do (If I misunderstand let me know but the admin guide does not cover more granular distinction).
Thanks!